绿色荧光配合物8-氨基喹啉硫氰酸镉的合成、晶体结构和荧光性质(英文) |
A Green Luminescent Cadmium Complex Containing 8-Aminoquinoline Ligand: Synthesis, Crystal Structure and Emission Spectra |
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关键词: 镉的配合物 晶体结构 荧光性质 |
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Abstract: A complex, Cd(8-aminoql)(SCN)2 (1) (8-aminoql=8-aminoquinoline), was synthesized and structurally characterized. The Cd2+ ion exhibits distorted octahedral coordination geometry and each SCN- anions bridging the neighboring Cd(8-aminoql)2+ units form a 2D sheet coordination polymer, and further extended into a 3D supramo-lecular structure through π-π weak interactions. The complex emits green luminescence at room temperature. CCDC: 737144. |
Keywords: cadmium complex crystal structure luminescence |
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徐 衡,黄良芳,任小明.绿色荧光配合物8-氨基喹啉硫氰酸镉的合成、晶体结构和荧光性质(英文)[J].无机化学学报,2010,26(1):171-175. |
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