| 氢键构筑具有三维结构的配合物[Cu(N-phthgly)2(H2O)2]·C2H5OH的合成及晶体结构 |
| Synthesis and Crystal Structure of a New 3D Complex [Cu(N-phthgly)2(H2O)2]·C2H5OH Constructed by Hydrogen Bonds |
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| 摘要: |
| 关键词: 铜(Ⅱ) 邻苯二甲甘氨酸 晶体结构 氢键 |
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| Abstract: A copper(Ⅱ) complex [Cu(N-phthgly)2(H2O)2]·C2H5OH(N-Hphthgly=N-phthaloylglycine) has been synthesized and characterized by elemental analysis, infrared spectroscopy and X-ray crystallography. The complex crystallizes in triclinic space group P1 with a=0.472 90(7) nm, b=1.080 01(13) nm, c=1.154 02(15) nm, α=74.360 0(10)°, β=79.151 0(10)°, γ=87.918(2)°, V=0.557 37(13) nm3, Z=1. The central copper atom allows the formation coordination environment with two O(5) atoms of two water ligands and two O(1) atoms of two N-phthgly ligands. The complex forms a step-like 3D structure through the three types of O-H…O hydrogen bonds and the Cu…O weak interaction. CCDC: 712945. |
| Keywords: copper(Ⅱ) N-Hphthgly crystal structure hydrogen bond |
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| 代永成,周丽丽,吴界强,张园园,金琼花.氢键构筑具有三维结构的配合物[Cu(N-phthgly)2(H2O)2]·C2H5OH的合成及晶体结构[J].无机化学学报,2009,25(12):2202-2206. |
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