十一烯酸邻菲咯啉铜(Ⅱ)配合物的合成、表征、晶体结构及与DNA作用 |
Synthesis, Characterization, Crystal Structure and Interaction with DNA of Copper(Ⅱ) Complex with Undecylenic Acid and 1,10-Phenanthroline |
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关键词: 铜(Ⅱ)配合物 十一烯酸 邻菲咯啉 晶体结构 DNA |
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Abstract: A copper(Ⅱ) complex Cu(C11H19O2)2(phen)(H2O), (C11H19O2=undecylenic acid, phen=1,10-phenanthroline), was synthesized and characterized by elemental analysis, IR and TG-DTG. Its crystal structure was determined by single crystal X-ray diffraction method. The complex, C34H48N2O5Cu, crystallizes in the triclinic system, space group P1. The interaction of complex with DNA was also studied by ethidium bromide (EB) fluorescence spectroscopy. CCDC: 729209. |
Keywords: copper(Ⅱ) complex undecylenic acid 1,10-phenanthroline crystal structure DNA |
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咸会朵,刘建风,赵国良.十一烯酸邻菲咯啉铜(Ⅱ)配合物的合成、表征、晶体结构及与DNA作用[J].无机化学学报,2009,25(11):2066-2069. |
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