| 一维链{[Mn2(2，2′-bipy)4(3，3′-tda)]·2ClO4}n配合物的合成、结构与磁性研究 |
| Synthesis, Structure and Magnetic Property of 1D Complex {[Mn2(2,2′-bipy)4(3,3′-tda)]·2ClO4}n |
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| 摘要: |
| 关键词: Mn(Ⅱ)配合物 丙二酸硫醚 2，2′-联吡啶 磁性 |
| 基金项目: |
| Abstract: By using 3,3′-thiodipropionic acid (3,3′-tdaH2) as typical ligand and 2,2′-bipyridine(2,2′-bipy) as supporting ligand, a 1D complex {[Mn2(2,2′-bipy)4(3,3′-tda)]·2ClO4}n (1) was synthesized and characterized by X-ray diffraction single crystal structure analysis, elemental analysis and IR spectra. Variable-temperature magnetic susceptibility was measured in the range 2~300 K. Research of magnetism shows weak antiferromagnetic interaction between the adjacent manganese(Ⅱ) ions in the complex. CCDC: 600473 |
| Keywords: Mn(Ⅱ) complex 3,3′-thiodipropionic acid 2,2′-bipyridine magnetic property |
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| 刘艳华,李 冰,顾 文,刘 欣.一维链{[Mn2(2，2′-bipy)4(3，3′-tda)]·2ClO4}n配合物的合成、结构与磁性研究[J].无机化学学报,2009,25(10):1889-1892. |
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