| 配位聚合物[Zn(PDA)(obix)]的合成、晶体结构和荧光性质(英文) | |
| Synthesis, Crystal Structure and Luminescent Property of Coordination Polymer [Zn(PDA)(obix)] | |
| 摘要: | |
| 关键词: 锌的配位聚合物 晶体结构 柔性配体 荧光性质 | |
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| Abstract: Hydrothermal reaction between 1,4-phenylenediacetic acid (H2PDA) and Zn(NO3)2·6H2O at the presence of the second ligand of 1,2-bis((1H-imidazol-1-yl) methyl)benzene (obix) yields a new 2D metal-organic coordination polymer [Zn(PDA)(obix)] (1), which has been characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy and thermal analysis. Complex 1 presents a two-dimensional (2D) sheet structure and displays strong luminescent emission at room temperature. CCDC: 716984. | |
| Keywords: zinc(Ⅱ) complex crystal structure flexible ligand luminescence | |
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| 朱 坤,许焕民,刘光祥,黄荣谊,任小明.配位聚合物[Zn(PDA)(obix)]的合成、晶体结构和荧光性质(英文)[J].无机化学学报,2009,25(9):1677-1681. | |
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