| 镉(Ⅱ)与对乙酰氨基苯甲酸、4，4′-联吡啶配位聚合物的合成、晶体结构及荧光性质(英文) |
| Synthesis, Crystal Structure and Fluorescence Characterization of Cadmium(Ⅱ) Coordination Polymer with 4-Acetamidobenzoic Acid and 4,4′-Bipyridine |
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| 摘要: |
| 关键词: 镉(Ⅱ)配合物 对乙酰氨基苯甲酸 液层扩散法 晶体结构 |
| 基金项目: |
| Abstract: The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4′-bipy)2]·(4,4′-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4′-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals, forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4′-bipy molecules and the complex molecule forms an one-dimensional double-chain structure. The luminescent properties of the complex were studied. CCDC: 734878. |
| Keywords: cadmium(Ⅱ) complex 4-acetamidobenzoic acid liquid diffusion method crystal structure |
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| 杨颖群,李昶红,李 薇,易正戟.镉(Ⅱ)与对乙酰氨基苯甲酸、4，4′-联吡啶配位聚合物的合成、晶体结构及荧光性质(英文)[J].无机化学学报,2009,25(7):1304-1307. |
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