| 配合物Zn(TC-TTF)0.5(bipy)2(CH3OH)的合成与结构表征 |
| Synthesis and Structure Characterization of Zn(TC-TTF)0.5(bipy)2(CH3OH) |
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| 摘要: |
| 关键词: 锌配位聚合物 四硫富瓦硫烯四羧酸 联吡啶 晶体结构 氢键 |
| 基金项目: |
| Abstract: A zinc coordination polymers, Zn(TC-TTF)0.5(bipy)2(CH3OH) (TC-TTF=tetra(carboxyl)tetrathiafulvalene, bipy=4,4′-bipyridine), has been prepared by solvothermal reaction and characterized by element analysis, IR spectra and X-ray diffraction single-crystal structure analysis. The title complex crystallizes in monoclinic space group C2/c. Each ZincⅡ is six-coordinated to three O atoms from two (TC-TTF)4- ligands, one oxygen atom from methanol and two nitrogen atoms from bipy molecule forming a distorted octahedral coordination geometry. The adjacent ZincⅡ ions are intraconnected by the carboxyl groups of the (TC-TTF)4- ligands and bipyridine to form a 3D network framework. CCDC: 684182. |
| Keywords: Zn coordination polymer H4(TC-TTF) bipyridine crystal structure hydrogen bond |
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| 韩银锋,李小燕,李季坤,郑泽宝,吴仁涛,鲁敬荣.配合物Zn(TC-TTF)0.5(bipy)2(CH3OH)的合成与结构表征[J].无机化学学报,2009,25(7):1290-1294. |
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