| 1，5-二硒杂[5]二茂铁环蕃的铜(Ⅰ)配合物的合成、晶体结构和电化学性质研究(英文) |
| Copper(Ⅰ) Complex of 1,5-Diselena[5]ferrocenophane: Synthetic, Crystallographic and Electrochemical Study |
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| 摘要: 合成了1，5-二硒杂[5]二茂铁环蕃的铜(Ⅰ)配合物，并用X-射线衍射单晶结构分析确定了其结构。配体的较小环径导致与铜离子配位时必须改变构型。电化学研究表明，由于2个二茂铁基团Fe…Fe的化学键距离为1.269(2)~1.277(3) nm，因此存在强电化学联系。 |
| 关键词: 1，5-二硒杂[5]二茂铁环蕃 铜 晶体结构 电化学 |
| 基金项目: |
| Abstract: The copper(Ⅰ) complex of 1,5-diselena[5]ferrocenophane (L) has been synthesized and the X-ray crystal structure is reported. The small cavity of the macrocyclic ligand means that the ring must undergo a conformational change to allow coordination. Electrochemical studies showed that electronic communication between ferrocenylene groups was observed in the copper complex where the through-bond Fe…Fe distances are in the range of 1.269(2)~1.277(3) nm. CCDC: 699681. |
| Keywords: 1,5-diselena[5]ferrocenophane copper crystal structure electrochemistry |
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| 景 苏,李志文,顾诚云.1，5-二硒杂[5]二茂铁环蕃的铜(Ⅰ)配合物的合成、晶体结构和电化学性质研究(英文)[J].无机化学学报,2009,25(7):1212-1216. |
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