| 温和条件原位配体反应合成铁四氮唑配合物及其晶体结构 | |
| Crystal Structure of An Ion Coordination Compound with Tetrazolyl Ligand Through In-situ Reaction under Mild Condition | |
| 摘要: 利用2-氰基吡啶与叠氮阴离子，在开放体系、温和条件下发生Demko-Sharpless原位配体反应，合成得到铁四氮唑配合物[Fe(2-PTZ)2(H2O)2]。该配合物为单核结构，其晶体属单斜晶系，P21/c空间群。配合物通过分子间的氢键及错位的面对面π-π堆积作用形成三维超分子体系。 | |
| 关键词: 原位配体反应 四氮唑 铁 晶体结构 | |
| 基金项目: | |
| Abstract: Using the Demko-Sharpless′ method, a very effective method for tetrazole compound, a ion(Ⅱ) complex has been synthesized and structurally characterized, which was obtained under open system and mild condition by in-situ ligand reaction. The complex [Fe(2-PTZ)2(H2O)2] (1) crystallized in monoclinic, space group P21/c with a=0.810 4(2) nm, b=1.288 0(3) nm, c=0.733 13(18) nm, β=95.974(5) °, V=0.761 1(3) nm3, Z=2, and formed a 3D supramolecular networks through intermolecular hydrogen bond and off-set face-to-face π-π stacking. CCDC: 734879. | |
| Keywords: in-situ ligand reaction tetrazole ion(Ⅱ) crystal structure | |
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| 王榆元,王小峰,聂长明,刘慧君,夏良树,王宏青,肖新荣,王晓晴.温和条件原位配体反应合成铁四氮唑配合物及其晶体结构[J].无机化学学报,2009,25(7):1194-1198. | |
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