| 3-甲基-4-对甲苯基-5-(2-吡啶基)-1，2，4-三唑-铜(Ⅱ)配合物(英文) |
| Copper(Ⅱ) Complex Based on 3-Methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole |
|
| 摘要: |
| 关键词: 铜(Ⅱ)配合物 晶体结构 荧光性质 |
| 基金项目: |
| Abstract: A copper(Ⅱ) complex [CuL(H2O)(Sal)]·0.5H2O was obtained by the reaction of copper(Ⅱ) salicylate with 3-methyl-4-(4-methylphenyl)-5-(2-pyridyl)-1,2,4-triazole (L) in ethanol-water solution at room temperature. The crystal belongs to triclinic system with space group P1, and a=0.913 6(4) nm, b=1.122 2(5) nm, c=1.263 3(7) nm, α=67.10(2)°, β=76.31(3)°, γ=68.17(2)°, V= 1.101(1) nm3, Z=2. The final refinement gave R1=0.039 8 and wR2=0.106 0 for 3 453 reflections with I>2σ(I). This complex is a good purple fluorescent material in solid state at room temperat-ure. CCDC: 685713. |
| Keywords: copper(Ⅱ) complex crystal structure fluorescence |
| |
| 摘要点击次数: 1549 |
| 全文下载次数: 1712 |
| 王作祥,宫晓宁,瞿志荣,吴平锋,张晓明.3-甲基-4-对甲苯基-5-(2-吡啶基)-1，2，4-三唑-铜(Ⅱ)配合物(英文)[J].无机化学学报,2009,25(3):567-570. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
