| Abstract: One dimensional chain Zinc(Ⅱ) coordination polymer [Zn(4,4′-bipy)·(o-ABA)2·(H2O)2]n has been synthesi-zed and in the solvent mixture of water and alcohol with o-acetamidobenzoic acid, 4,4′-bipyridine and zinc per-chlorate anhydrous. The crystal of the title polymer belongs to tetragonal space group P43212 with a=1.605 27(6) nm, b=1.605 27(6) nm, c=2.108 96(15) nm; V=5.434 6(5) nm3, Dc=1.501 g·cm-3, Z=8, F(000)=2 544, R1=0.030 1, wR2=0.067 7. The crystal structure shows that the zinc ion is coordinated with two nitrogen atoms of one 4,4′-bipyridine molecule and four oxygen atoms from two o-acetamidobenzoic acid molecules and two water molecules respectively, forming a distorted octahedral coordination geometry. The result of TG analysis shows that the title complex was stable under 200.0 ℃. CCDC: 701996. |
