| 三维异核Mn-Na配合物[MnNa(N3)4(C5H5N)4]的合成与表征(英文) |
| Synthesis and Characterization of a Three-dimensional Heteronuclear Mn-Na Complex [MnNa(N3)4(C5H5N)4] |
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| 摘要: |
| 关键词: 异核配合物 叠氮酸根 合成 拓扑 |
| 基金项目: |
| Abstract: Azide-containing coordination polymers have received considerable attention for the construction of new molecule-based magnets. A three dimensional heteronuclear Mn-Na compound [MnNa(N3)4(C5H5N)4] was obtained by reaction of [Mn3O(O2CCH3)6(py)3]ClO4 and NaN3 in pyridine solvents. The title compound crystallizes in monoclinic space group C2/c, a=1.536 6(2), b=1.045 3(2), c=1.576 3(2) nm, β=90.309(3)°, V=2.531 8(6) nm3, Z=4. In the structure, each Mn3+ and Na+ ion coordinated with four N atoms from four N3- and two N atoms from two pyridine molecules. Each pair of Mn3+ and Na+ ion are linked by N3- bridges into a 3D polymer with PtS topology. CCDC: 706250. |
| Keywords: heteronuclear complex azido synthesis topology |
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| 摘要点击次数: 1889 |
| 全文下载次数: 1923 |
| 马运声,王 君,袁荣鑫.三维异核Mn-Na配合物[MnNa(N3)4(C5H5N)4]的合成与表征(英文)[J].无机化学学报,2008,24(12):2043-2046. |
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