| 一个多酸簇合物[Cu4(PPh3)6][Mo8O26]的合成、晶体结构和非线性光学性质(英文) | |
| Synthesis, Crystal Structure and Nonlinear Optical Properties of an Oxomolybdate-copper Cluster [Cu4(PPh3)6][Mo8O26] | |
| 摘要: 本文报道了一个多酸簇合物[Cu4(PPh3)6][Mo8O26]的合成、X-射线单晶结构分析及IR、XRD表征。单晶结构表明中心对称的[Mo8O26]4-是由8个共边的MoO6八面体组成。该化合物具有较好的三阶非线性光学性质，其三阶非线性吸收和折射系数分别为12.9×10-11 MKS和3.13×10-11 esu。 | |
| 关键词: 晶体结构 簇合物 非线性光学 多酸 | |
| 基金项目: | |
| Abstract: In this article, an oxomolybdate-copper cluster, [Cu4(PPh3)6][Mo8O26](1), has been synthesized and cha-racterized by single-crystal X-ray diffraction structure analysis, IR spectrum and XRD analysis. The crystal structure shows that the centrosymmetric [Mo8O26]4- anion is built with eight MoO6 edge-shared octahedra, which belongs to the typical β-octamolybdate arrangement. The title cluster exhibits nonlinear optical properties (NLO) with effective third-order NLO absorptive index α2 and refractive index n2 value 12.9×10-11 MKS and 3.13×10-11 esu, respectively. CCDC: 632477. | |
| Keywords: crystal structure cluster nonlinear optics oxomolybdate-copper | |
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| 朱英贵,居学海,宋瑛林,黄克旋,李一志,郑和根.一个多酸簇合物[Cu4(PPh3)6][Mo8O26]的合成、晶体结构和非线性光学性质(英文)[J].无机化学学报,2008,24(12):2029-2034. | |
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