| 系列纳米结构锰氧化物的水热合成(英文) | |
| Synthesis of Various Nanostructured Manganese Oxides via Facile Hydrothermal Reaction | |
| 摘要: 以KMnO4为锰源、抗坏血酸(AA)为还原剂，采用水热法制备系列纳米结构锰氧化物。通过调节反应物的物质的量的比、水溶液的pH值、反应温度和反应时间，制备出了不同纳米结构的锰氧化物，包括Mn3O4纳米粒子、MnOOH、α-MnO2和β-MnO2纳米棒。采用XRD和TEM测试技术对合成产物进行了表征，同时对其反应机理进行了探讨。 | |
| 关键词: 水热法 纳米结构锰氧化物 氧化还原反应 机理 | |
| 基金项目: | |
| Abstract: A versatile hydrothermal reaction between KMnO4 and ascorbic acid(AA) was developed to synthesize manganese compounds. A variety of nanostructured manganese oxides including Mn3O4 nanoparticles, MnOOH, α-MnO2 and β-MnO2 nanorods have been prepared through adjusting the molar ratio of the reactants, pH value of the aqueous solution, reaction temperature and reaction time. The products were characterized by X-ray powder diffraction(XRD) and transmission electron microscopy(TEM). The possible reaction mechanism was discussed. | |
| Keywords: Hydrothermal method nanostructured manganese oxides redox reaction mechanism | |
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| 杨则恒,周晨旭,宋新民,张卫新,张 娜.系列纳米结构锰氧化物的水热合成(英文)[J].无机化学学报,2008,24(10):1695-1700. | |
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