| 超临界水中含碳酸根羟基磷灰石的快速连续合成(英文) |
| Rapid and Continuous Synthesis of Carbonated Hydroxyapatite in Supercritical Water |
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| 摘要: |
| 关键词: 含碳酸根羟基磷灰石 超临界水 连续合成 |
| 基金项目: |
| Abstract: Carbonated hydroxyapatites(CHA) were rapidly and continuously synthesized in supercritical water by using a tubular reactor. The effects of reaction time and the ratio of PO43-/CO32- on the apatite structure were investigated by using XRD, FTIR and TEM. Results showed that 30 seconds were enough to produce fully crystalline CHA nano-rods, ca. 20×70 nm in size, at 380 ℃ and 24 MPa. When the ratio of PO43-/CO32- was not less than 1, the CO32- ions mainly substituted for PO43- in apatite structure; but CO32- ions could react with Ca2+ to form CaCO3 phase when the ratio of PO43-/CO32- was less than 1. |
| Keywords: carbonated hydroxyapatite supercritical water continuous synthesis |
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| 于文利,林长春,洪 流,赵亚平,饶群力.超临界水中含碳酸根羟基磷灰石的快速连续合成(英文)[J].无机化学学报,2008,24(9):1539-1542. |
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