以冠醚为骨架的多足配体稀土配合物的合成、表征及荧光性质研究 |
Synthesis, Characterization and Luminescent Properties of Rare Earth Complexes with Podand Ligand Using Crown Ether as Skeleton |
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摘要: |
关键词: 多足配体 冠醚 稀土配合物 荧光性质 |
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Abstract: A novel podand ligand using crown ether as skeleton and N-benzylsalicylamide as functional arms, 4,5-bi{2′-methylbenzeneaminoformyl)phenoxyl]methyl}-benzo-12-crown-4 (L), and its rare earth nitrate complexes have been synthesized. These complexes were characterized by elemental analysis, conductivity measurements and IR spectroscopy. Spectrographic analyses suggest that the complexes show a similar coordination mode. At the same time, the luminescent properties of the Eu(Ⅲ) and Tb(Ⅲ) complexes were also studied. |
Keywords: podand ligand crown ether rare earth complex luminescent property |
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柳佃义,闫旭焕,唐 瑜,刘伟生,谭民裕.以冠醚为骨架的多足配体稀土配合物的合成、表征及荧光性质研究[J].无机化学学报,2008,24(8):1356-1359. |
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