| 具有二维网格结构的5-(4-硝基苯基)四唑-锌(Ⅱ)配合物(英文) |
| A Novel 2D Zn-coordination Polymer Based on a 5-(4-nitrophenyl)-1H-tetrazole Ligand |
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| 摘要: |
| 关键词: 锌配合物 水热合成 晶体结构 荧光性质 |
| 基金项目: |
| Abstract: A zinc(Ⅱ) complex [(5-(4-nitrophenyl)tetrazolato)2Zn]n was obtained by the hydrothermal treatment of ZnBr2 and NaN3 with 4-nitrobenzonitril in water at 120 ℃ in Pyrex tube. The crystal belongs to orthorhombic system with space group Pbcn, and a=1.040 7(5) nm, b=1.382 1(7) nm, c=2.435 1(13) nm, V=3.503(3) nm3, Z=8. This complex is a good blue fluorescent material in solid state at room temperature. CCDC: 684226. |
| Keywords: zinc complex hydrothermal synthesis crystal structure fluorescence |
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| 肖 杰,赵玉媛,王文祥,赵 红.具有二维网格结构的5-(4-硝基苯基)四唑-锌(Ⅱ)配合物(英文)[J].无机化学学报,2008,24(8):1347-1351. |
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