| 含硫多吡啶配体及其过渡金属配合物的合成、表征与结构 |
| Syntheses, Characterization and Structures of Transition Metal Complexes with a Polypyridyl Ligand Bearing S-donors |
|
| 摘要: 本文报道1个含硫多吡啶配体5，5′-二(2-吡啶硫)甲基-2，2′-联吡啶(L)及其3个过渡金属配合物{[AgL](ClO4)}∞ (1)，[CuLCl2] (2)和[Mn(L)3](ClO4)2(H2O)0.5 (3)的合成及结构表征 |
| 关键词: 含硫多吡啶配体 银(Ⅰ)配合物 铜(Ⅱ)配合物 锰(Ⅱ)配合物 晶体结构 |
| 基金项目: |
| Abstract: Three transition metal complexes with a new polypyridyl ligand bearing S-donors 5,5′-bis(2-pyridylsulfanylmethyl)-2,2′-bipyridine (L), {[AgL](ClO4)}∞ (1), [CuLCl2] (2) and [Mn(L)3](ClO4)2(H2O)0.5 (3), were synthesized and structurally characterized by IR and single crystal X-ray diffraction structural analysis. 1 has a 1D chain structure, whereas 2 and 3 take mononuclear structures. The structural differences of the three complexes were attributable to the difference of metal ions. CCDC: 686045, 1; 686046, 2; 686047, 3. |
| Keywords: polypyridyl ligand bearing S-donors Ag(Ⅰ) complex Cu(Ⅱ) complex Mn(Ⅱ) complex crystal structure |
| |
| 摘要点击次数: 2466 |
| 全文下载次数: 3864 |
| 胡同亮,卜显和.含硫多吡啶配体及其过渡金属配合物的合成、表征与结构[J].无机化学学报,2008,24(8):1294-1299. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
