| 1，4-二氮杂二环[2.2.2]辛烷-1，4-二乙酸配合物的合成、结构与磁性 |
| Synthesis, Structures and Magnetic Properties of Coordination Compounds Based on 1,4-diazoniabicyclo[2.2.2]octane-1,4-diacetate |
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| 摘要: 合成了{[M(L)2(H2O)2](ClO4)2·4H2O}n(M=Cu 1，Co 2；L=1，4-二氮杂二环[2.2.2]辛烷-1，4-二乙酸)，并进行了元素分析、红外、热重、变温磁化率等表征。单晶结构表明这2个配合物属于单斜晶系，P21/c空间群。Cu(Ⅱ)和 |
| 关键词: Cu(Ⅱ)配合物 Co(Ⅱ)配合物 1，4-二氮杂二环[2.2.2]辛烷-1，4-二乙酸 磁性 晶体结构 |
| 基金项目: |
| Abstract: Two coordination compounds, {[M(L)2(H2O)2](ClO4)2·4H2O}n (M=Cu 1, Co 2; L=1,4-diazoniabicyclo[2.2.2]octane-1,4-diacetate), were synthesized and characterized by elemental analysis, IR, TGA and magnetic susceptibilities. Single-crystal structures show the two compounds both crystallize in monoclinic system, space group P21/c. Cu(Ⅱ) and Co(Ⅱ) ions are coordintated with six oxygen atoms from two water molecules and four ligands to form an octahedral geometry. Each ligand links two metal ions in a μ2-bridge coordination mode and two-dimensional wavelike structures are formed. Magnetic studies showed that weak antiferromagnetic interactions existed between the Cu(Ⅱ) ions in 1, and Co(Ⅱ) ions were located in a moderate ligand field in 2. CCDC: 684712, 1; 684713, 2. |
| Keywords: Cu(Ⅱ) complex Co(Ⅱ) complex 1,4-diazoniabicyclo[2.2.2]octane-1,4-diacetate magnetic properties crystal structure |
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| 张瑞凤,师 唯,程 鹏.1，4-二氮杂二环[2.2.2]辛烷-1，4-二乙酸配合物的合成、结构与磁性[J].无机化学学报,2008,24(8):1272-1277. |
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