| 一维梯状配位聚合物{[Cu3(H2O)8(4，4′-bipy)2(smbdc)2]·6H2O}n的合成与晶体结构 |
| Synthesis and Crystal Structure of One-dimensional Ladder Polymer {[Cu3(H2O)8(4，4′-bipy)2(smbdc)2]·6H2O}n |
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| 摘要: |
| 关键词: 5-磺酸基间苯二甲酸 一维梯形网络结构 第二构筑单元 |
| 基金项目: |
| Abstract: In the title complex, {[Cu3(H2O)8(4，4′-bipy)2(smbdc)2]·6H2O}n, Cu1 and Cu2 have different coordination environment. The 5-sulfo-1,3-benzenedicarboxylic acid (smbdc3-) ligands form one-dimensional zigzag chains linked by Cu atoms. The two adjacent zigzag chains extend into one-dimensional ladder frameworks bridged by a secondary building unit [Cu(H2O)4(4,4′-bipy)2]2+. The hydrogen-bond interactions between chains make the complex a three-dimensional open supramolecular network. CCDC: 670975. |
| Keywords: 5-sulfoisophthalate acid one-dimensional ladder frameworks secondary building units |
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| 摘要点击次数: 1388 |
| 全文下载次数: 1894 |
| 周以力,何洪银.一维梯状配位聚合物{[Cu3(H2O)8(4，4′-bipy)2(smbdc)2]·6H2O}n的合成与晶体结构[J].无机化学学报,2008,24(2):290-292. |
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