| 含二茂铁羧酸的混配双核镉配合物的晶体结构及电化学性质 | |||||||||||||
| Crystal Structure and Electrochemical Property of A Binuclear Cadmium Complex with Ferrocenyldicarboxylate | |||||||||||||
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| 摘要: 以二茂铁双甲酸、1，10-邻菲咯啉为配体，得到了一个新颖的双核镉配合物，通过元素分析，IR，和X-射线单晶衍射等分析手段，确证了标题化合物的组成和结构，单晶结构解析表明，配合物属于单斜晶系，C2/c空间群。 | |||||||||||||
| 关键词: 二茂铁双甲酸 双核配合物 晶体结构 电化学性质 | |||||||||||||
| 基金项目: | |||||||||||||
| Abstract: A novel binuclear cadmium complex was obtained by the reaction of CdCl2 and 1,10-phen in methanol mixed with ferrocenyldicarboxylate. It has been characterized by IR, element analysis and X-ray diffraction. The crystallographic data were as follows: monoclinic system, space group C2/c, a=1.429 88(11) nm, b=2.368 82(18) nm, c=1.241 02(9) nm, β=96.285 0(10)°, V=4.178 2(5) nm3, Z=4, Dc=1.852 g·cm-3, μ=1.754 mm-1, F(000)=2 320. Final R=0.022 5, wR=0.054 5. CCDC: 635065. | |||||||||||||
| Keywords: ferrocenyldicarboxylate binuclear complex crystal structure electrochemical property | |||||||||||||
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| 吕恩年,张 峻,朱丽敏,徐 琰,樊耀亭.含二茂铁羧酸的混配双核镉配合物的晶体结构及电化学性质[J].无机化学学报,2008,24(2):201-204. | |||||||||||||
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