无机-高分子-无机多组分核壳纳米复合材料的制备和表征 |
Preparation and Characterization of Inorganic-Polymer-Inorganic Multicomponent Core-Shell Nanocomposite Material |
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关键词: 聚甲基丙烯酸甲酯 聚N-异丙基丙烯酰胺 四氧化三铁 银纳米粒子 复合材料 |
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Abstract: Fe3O4 nanoparticles were prepared by chemical co-precipitation using palmitic acid as surfactant, then a uniformly dispersed system of Fe3O4@Polymethylmethacrylates(PMMA) core-shell structure was obtained. Furtherm-ore, polymethylmethacrylates(PNIPAM) was encapsulated on the surface of the Fe3O4@PMMA core-shell nano-structure to get Fe3O4@PMMA@PNIPAM double shell-core composite structure. After that, the Ag nano-particles were assembled on the surface of Fe3O4@PMMA@PNIPAM taking advantage of coordination reaction between Ag+ and nitrogen atom on the amide group of PNIPAM. The magnetism of composites is convenient for the catalyst separation from the solution. |
Keywords: polymethylmethacrylates poly(N-isopropylacrylamide Fe3O4 Ag nanoparticles composite materials |
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朱冬妹,王 飞,韩 敏,李红变,徐 正.无机-高分子-无机多组分核壳纳米复合材料的制备和表征[J].无机化学学报,2007,23(12):2128-2132. |
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