6,6′-二硝基-2,2′-联苯酸铀(Ⅵ)配聚物(英文) |
Uranium(Ⅵ) Coordination Polymer with 6,6′-dinitro-biphenyl-2,2′-dicarboxylic Acid Ligand |
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摘要: |
关键词: 铀(Ⅵ)配合物 水热合成 晶体结构 |
基金项目: |
Abstract: Uranium(Ⅵ) complex {[UO2((R,S)-1,1′-biphenyl-6,6′-dinitro-2,2′-dicarboxylate)(H2O)](H2O)} was obtained by the hydrothermal treatment of UO2(NO3)2·6H2O with (R,S)-6,6′-dinitro-biphenyl-2,2′-dicarboxylic acid(BSNCA) (L) in water at 180 ℃ in Pyrex tube. The crystal belongs to triclinic system, space group P1, with a=0.903 45(14) nm, b=1.024 43(16) nm, c=1.058 95(16) nm, α=90.411(3)°, β=112.934(3)°, γ=92.554(3)°. CCDC: 659613. |
Keywords: uranium(Ⅵ) complex hydrothermal treatment crystal structure |
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瞿志荣.6,6′-二硝基-2,2′-联苯酸铀(Ⅵ)配聚物(英文)[J].无机化学学报,2007,23(12):2123-2125. |
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