具有自旋涨落性质的单一手性三核镍(Ⅱ)配合物(英文) |
Homochiral Trinuclear Nickel(Ⅱ) Complex with a Spin Fluctuation |
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摘要: |
关键词: 镍(Ⅱ) 同手性配合物 铁电性与铁磁性 自旋涨落 |
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Abstract: [Ni3O(TBPLA)(H2O)](ClO4)4(H2O)6 [TBPLA=(S)-1,1′,1″-2,4,6-trimethylbenzene-1,3,5-triyl)-tris(methylene)-tris-(pyrrolidine-2-carboxylate)] was found to possibly display multiferroic property (the coexistence of ferroelectricity and ferromagnetism). The magnetic property of this compound was studied and no magnetic hysteresis loop was found probably due to an intrinsic fluctuation for the magnetic exchange energy. |
Keywords: nickel(Ⅱ) homochiral coordination compound ferroelectricity and ferromagnetism spin fluctuation |
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王国喜,李 波,熊仁根,Tomoyuki Akutagawa.具有自旋涨落性质的单一手性三核镍(Ⅱ)配合物(英文)[J].无机化学学报,2007,23(11):1994-1996. |
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