| 一维链状镍配位聚合物{[Ni(4，4′-bipy)(2，4，6-TMBA)2(H2O)2]·(CH3OH)}n的合成、晶体结构及电化学性质 |
| Synthesis， Crystal Structure and Electrochemical Properties of One Dimensional Chain Coordination Polymer {[Ni(4，4′-bipy)(2，4，6-TMBA)2(H2O)2]·(CH3OH)}n |
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| 摘要: |
| 关键词: 镍(Ⅱ)配合物 合成 晶体结构 电化学性质 |
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| Abstract: One dimensional chain nickel(Ⅱ) coordination polymer has been synthesized with 2，4，6-trimethylbenz-oic acid， 4，4′-bipyridine and nickel perchlorate anhydrous， and characterized in the solvent mixture of water and methyl-alcohol. Crystal data for this complex: monoclinic， space group C2/c， a=2.154 7(7) nm， b=1.131 9(2) nm， c=1.655 7(8) nm， β=129.66(3)°， V=3.108 7(19) nm3， Dc=1.370 g·cm-3， Z=4， F(000)=1 360， final GooF=1.042， R1=0.034 4， wR2=0.078 7. The crystal structure shows that the nickel ion is coordinated with two nitrogen atoms of two 4，4′-bipyridine molecules and four oxygen atoms from two 2，4，6-trimethylbenzoic acid molecules and two water molecules， respectively， forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 649415. |
| Keywords: nickel(Ⅱ) complex synthesis crystal structure electrochemical property |
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| 杨颖群,李昶红,李 薇,匡云飞.一维链状镍配位聚合物{[Ni(4，4′-bipy)(2，4，6-TMBA)2(H2O)2]·(CH3OH)}n的合成、晶体结构及电化学性质[J].无机化学学报,2007,23(10):1815-1818. |
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