| 一维链状1，8-萘二酸四核锌配位聚合物[Zn4(1，8-nap)4(4，4′-bipy)2·0.5en·H2O]n的合成、结构、热稳定性及发光性质 | |
| Synthesis， Structure， Thermal Stability and Luminescence of a 1D Chain Coordination Polymer [Zn4(1，8-nap)4(4，4′-bipy)2·0.5en·H2O]n | |
| 摘要: | |
| 关键词: 羧酸锌配合物 晶体结构 合成 发光性质 | |
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| Abstract: A coordination polymer [Zn4(1，8-nap)4(4，4′-bipy)2·0.5en·H2O]n (where 1，8-nap is 1，8-naphthalenedi-carboxylate， 4，4′-bipy is 4，4′-bipyridine and en is ethylenediamine) has been hydrothermally synthesized and characterized by elemental analysis， IR， TG and single crystal X-ray diffraction. The title complex belongs to triclinic system with space group P1， a=1.026 94(2) nm， b=1.134 52(2) nm， c=1.348 64(3) nm， α=79.992°， β=73.838°， γ=84.246°， V=1.484 nm3， Z=1， Mr=1 478.59， Dc=1.655 g·cm-3， R=0.031 8， wR=0.087 6. The crystal structure of title complex shows that four 1，8-naphthalenedicarboxylate ligands coordinate with zinc atoms to form tetranuclear units which are further connected via 4，4′-bipy ligands to generate 1D double-chain structure. The luminescent property of the complex is also studied in this paper. CCDC: 657266. | |
| Keywords: zinc(Ⅱ) carboxylate complex crystal structure synthesis luminescent | |
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| 何银华,封 霞,冯云龙,孙 鸿,温一航.一维链状1，8-萘二酸四核锌配位聚合物[Zn4(1，8-nap)4(4，4′-bipy)2·0.5en·H2O]n的合成、结构、热稳定性及发光性质[J].无机化学学报,2007,23(10):1805-1808. | |
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