| 酰胺型三足体铜配合物[CuL][CuCl2(NO3)2]的合成及晶体结构 |
| Synthesis and Crystal Structure of the Copper(Ⅱ) Complex with an Amide-type Tripodal ligand， [CuL][CuCl2(NO3)2] |
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| 摘要: |
| 关键词: 酰胺型三足体 铜配合物 合成 晶体结构 |
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| Abstract: The title complex， [CuL][CuCl2(NO3)2] [L=N，N，N′，N′，N″，N″-Hexaisopropyl-2， 2′， 2″-Nitrilotris(2，1-ethoxy)triacetamide]， has been synthesized by using an amide-type tripodal ligand with Cu(NO3)2 and then characterized by X-ray single crystal structure analysis. It belongs to monoclinic，space group P21/c with a=1.522 7(2) nm，b=1.277 8(2) nm， c=2.184 5(4) nm， β=93.680(10)°， V=4.241 6(12) nm3， Z=4， Dc=1.401 Mg·m-3， μ=1.189 mm-1， F(000)=1 880， and final R1=0.050 9， wR2=0.125 3. The results show a Cu(Ⅱ) ion was encapsulated by the three chains of the cup-like heptadentate ligand and four-coordinated by the central nitrogen atom and three oxygen atoms from the ligand. CCDC: 648900. |
| Keywords: amide-type tripodal ligand copper complex synthesis crystal structure |
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| 范 军,章伟光,谭民裕,刘伟生,唐 瑜,郁开北.酰胺型三足体铜配合物[CuL][CuCl2(NO3)2]的合成及晶体结构[J].无机化学学报,2007,23(10):1793-1795. |
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