| 多元混配合物[Ni(NPA)2(Phen)(Ac)(H2O)]·H2O的合成、晶体结构 |
| Synthesis， Crystal Structure of Mixed-ligand Complexes [Ni(NPA)2(Phen)(Ac)(H2O)]·H2O |
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| 摘要: |
| 关键词: 镍(Ⅱ)配合物 N-苯基代邻氨基苯甲酸 晶体结构 π-π堆积作用 |
| 基金项目: |
| Abstract: A Nickle(Ⅱ) complex [Ni(NPA)2(Phen)(Ac)(H2O)]·H2O has been synthesized (NPA=N-phenylanthranilic acid， Phen=1，10-phenanthroline and Ac=acetate) and characterized by IR， elemental analysis and X-ray crystal structure determination. It crystallizes in triclinic system， space group P1 with a=0.891 25(2) nm， b=1.451 85(3) nm， c=1.485 54(3) nm， α=67.384(1)°， β=82.932(1)°， γ=85.168(1)°， V=1.759 50(6) nm3， Z=2， Dc=1.405 g·cm-3， F(000)=778， R1=0.032 3， wR=0.084 7. The crystal structure shows that the Nikcle(Ⅱ) ion is coordinated with two oxygen atoms from two N-phenylanthranilic acid，two nitrogen atoms from one 1，10-phenanthroline， two oxygen atoms from one acetate and one water respectively， forming a distorted octahedral coordination geometry. CCDC: 657265. |
| Keywords: nikcle(Ⅱ) complex N-phenylanthranilic acid crystal structure π-π aromatic interactions |
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| 匡云飞,陈志敏,李东平,邝代治.多元混配合物[Ni(NPA)2(Phen)(Ac)(H2O)]·H2O的合成、晶体结构[J].无机化学学报,2007,23(10):1777-1780. |
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