邻二氮菲苯妥英合锰(Ⅱ)三元配合物的合成、结构与抗微生物活性研究(英文) |
Synthesis, Crystal Structure and Antimicrobial Activity of a New Ternary Mixed Ligand Complex [Mn(pht)2(phen)] |
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摘要: |
关键词: Mn(Ⅱ)配合物 苯妥英 邻二氮菲 晶体结构 抗微生物活性 |
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Abstract: The title complex [Mn(pht)2(phen)] (Hpht=5,5-diphenylimidazoline-2,4-dione, phen=1,10-phenanthroline) was synthesized and characterized by elemental analysis, IR and X-ray diffraction single-crystal structure analysis. The compound crystallizes in the monoclinic system, space group C2/c with a=2.631 5(16) nm, b=0.924 5(6) nm, c=1.550 8(10) nm, β=116.231(7)°; V=3.384(4) nm3,Mr=737.66, Z=4, F(000)=1 524, Dc=1.448 g·cm-3, μ=0.446 mm-1, the final R=0.069 9 and wR=0.195 3. The complex was valued for its antimicrobial activity against some bacteria in vitro. It was found to be active against the four test bacterial organisms. CCDC: 616309. |
Keywords: manganese complex 5,5-diphenylimidazoline-2,4-dione 1,10-phenanthroline crystal structure antimicrobial activity |
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胡喜兰,许兴友,王大奇,许同桃,顾海星.邻二氮菲苯妥英合锰(Ⅱ)三元配合物的合成、结构与抗微生物活性研究(英文)[J].无机化学学报,2007,23(9):1675-1678. |
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