珍珠质基底上CaCO3晶体的仿生生长研究 |
Simulated Growth of CaCO3 Crystals on Nacreous Surface |
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摘要: |
关键词: CaCO3 晶体生长 生物矿化 珍珠质 |
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Abstract: A conventional vapor diffusion method was applied to in vitro precipitation of CaCO3 crystal. The morphologies and components of the deposit were characterized by SEM, Raman and X-ray diffraction. The results show that the surface of shell nacre promotes the nucleation of aragonite polymorphs of CaCO3, while suppresses the nucleation of calcite and vaterite. The active sites for the deposit, which subsequently transforms to faceted crystals, were only located on the edges of nacreous tablets. The tower-like deposit observed after 24 h was consisted of only aragonite crystals layered along the direction of the c-axis of nacreous tablets. |
Keywords: CaCO3 crystal growth biomineralization nacre |
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罗程,谢雷,王小祥,王慧明.珍珠质基底上CaCO3晶体的仿生生长研究[J].无机化学学报,2007,23(6):1107-1110. |
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