牛磺酸缩5-溴水杨醛席夫碱合镍(II)配合物的合成及晶体结构 | |||||||||||
Synthesis, Crystal Structure of a Complex with Nickel(II), Taurine 5-bromosalicyladehyde Schiff Base | |||||||||||
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关键词: 镍配合物 牛磺酸 晶体结构 | |||||||||||
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Abstract: The reaction of Ni(Ac)2, Taurine, 5-bromo-salicylaldehyde afford a complex, [Ni(C9H8BrNO4S)(H2O)3]·H2O. Its structure has been determined by single crystal X-ray diffraction. It crystallizes in monoclinic, P21/c, a=1.479 98(6) nm, b=1.397 97(6) nm, c=0.746 60(3) nm, β=99.364(2)°, V=1.524 11(11) nm3. Nickel(II) coordinated with six atoms, forming a octahedron. These octahedrons are further interlinked by the hydrogen bonds. CCDC: 639681. | |||||||||||
Keywords: complex of nickel taurine crystal structure | |||||||||||
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钟凡,应少明,许亚平,王琪.牛磺酸缩5-溴水杨醛席夫碱合镍(II)配合物的合成及晶体结构[J].无机化学学报,2007,23(5):854-856. | |||||||||||
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