| 一种含[Ni(CN)4]2-和[Cu(pn)]2+构筑元组成的超分子配合物的合成、单晶结构和磁学性质(英文) |
| Synthesis, Crystal Structure and Magnetic Property of a Cyano-Bridged 3D Heterometallic Supramolecular Complex Containing [Ni(CN)4]2- and [Cu(pn)]2+ Tectons |
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| 摘要: |
| 关键词: 超分子配合物 单晶结构 磁性 |
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| Abstract: A cyano-bridged heterometallic supramolecular complex {[Cu(pn)]3[Ni(CN)4]3}n (1) has been synthesized and structurally characterized by single crystal X-ray diffraction. 1 displays an interesting 3D structure formed by μ4, μ3-[Ni(CN)4]2- tectons bridging five-coordinated and six-coordinated Cu(II) ions. The magnetic property shows that 1 behaves as weakly ferromagnetic interactions between the adjacent Cu(II) ions through the diamagnetic spacer NC-Ni-CN. CCDC: 624387. |
| Keywords: supramolecular complex single crystal structure magnetic property |
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| 苏育志,刘兆清,董文.一种含[Ni(CN)4]2-和[Cu(pn)]2+构筑元组成的超分子配合物的合成、单晶结构和磁学性质(英文)[J].无机化学学报,2007,23(4):713-716. |
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