新颖的镧-2-氟苯甲酸及2,2′-联吡啶配合物的合成与晶体结构(英文) |
Synthesis, Crystal Structure and Properties of a Novel Lanthanum 2-fluorobenzoate Complex Containing 2,2′-bipyridine |
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摘要: |
关键词: 镧配合物 2-氟苯甲酸 2,2′-联吡啶 晶体结构 |
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Abstract: 2-fluorobenzoic acid (2-HFBA) and 2,2′-bipyridine (2,2′-bpy) was used as ligands to react with lanthanum to obtain a complex, [La(2-FBA)3·(2,2′-bpy)]2. The structure of the complex contains three independent molecules. In two of them, the two central metal ions are connected together through four 2-FBA groups by bidentate bridging and chelating-bridging two modes. In another, the two central metal ions are connected together through four bidentate bridging 2-FBA groups. CCDC: 237658. |
Keywords: lanthanum complex 2-fluorobenzoate 2,2′-bipyridine crystal structure |
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李夏.新颖的镧-2-氟苯甲酸及2,2′-联吡啶配合物的合成与晶体结构(英文)[J].无机化学学报,2007,23(3):489-493. |
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