明胶基多孔碳球电极材料的制备及电化学性能研究 |
Gelatin-based Porous Carbon Beads: Preparation and Application as Electrodes in Super-capacitors |
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摘要: |
关键词: 明胶基多孔碳球 活化温度 超级电容器 性能 |
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Abstract: Gelatin-based porous carbon beads have been fabricated from gelatin micro-spheres by means of solidification, carbonization and chemical activation with KOH. The physical properties of gelatin-based porous carbon beads were studied by a t-plot method based on N2 adsorption isotherms. The gelatin-based porous carbon beads activated at 800 ℃ exhibited the largest specific surface area and resulted in the highest capacitance. Carbon/carbon super-capacitors cells assembled with the electrode materials in 1.0 mol·L-1 NEt4BF4 / acetonitrile electrolyte have also been studied. The electrochemical properties of gelatin-based porous carbon beads electrode were studied by using constant-current discharge tests. The results indicate that the gelatin-based porous carbon beads electrode is with good cycling stability and specific capacitance of 119.8 F·g-1. |
Keywords: gelatin-based carbon beads activation temperature super-capacitor properties |
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慈颖,葛军,王小峰,陈文浩,郭燕川,陈丽娟.明胶基多孔碳球电极材料的制备及电化学性能研究[J].无机化学学报,2007,23(2):365-368. |
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