碳纳米管的功能化及其电化学性能 |
Functionalization and Electrochemical Performance of Carbon Nanotubes |
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关键词: 功能化 碳纳米管 比电容 |
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Abstract: Carbon nanotubes with arylsulfonic acid groups were prepared using azobisisobutyronitrile as an initiator via the surface modification of carbon nanotubes by aminobenzenesulfonic acid in fuming sulfuric acid. The electrochemical performances of the functional multi-wall carbon nanotubes used as active electrode materials were tested with cyclic voltammetry and galvanostatic charge-discharge. The results show that the functional multi-wall carbon nanotubes electrodes exhibit larger capacitance. The specific capacitance has been enchanced up to 50 F·g-1 at 3 mA discharging compared to that of carbon nanotubes coped with fuming sulfuric acid (22 F·g-1 at 3 mA) and carbon nanotubes without treatment (15 F·g-1 at 3 mA). |
Keywords: functionalization carbon nanotubes specific capacitance |
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米红宇,张校刚,吕新美,王兴磊.碳纳米管的功能化及其电化学性能[J].无机化学学报,2007,23(1):159-163. |
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