三(2-氨基乙基)胺-镉(Ⅱ)-2-甲基咪唑三元配合物的合成、结构与抗微生物活性(英文) |
Synthesis, Crystal Structure and Antimicrobial Activity of a Ternary Mixed Ligand Complex [Cd(tren) (meim)](ClO4)2 (tren=tris(2-aminoethyl)amine, meim=2-Methylimidazole) |
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摘要: |
关键词: Cd(Ⅱ)配合物 三(2-氨基乙基)胺 2-甲基咪唑 晶体结构 抗微生物活性 |
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Abstract: The complex [Cd(tren)(meim)](ClO4)2 was synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The compound crystallizes in monoclinic system, space group P21/m with a=0.786 8(2) nm, b=0.834 2(2) nm, c=1.496 2(4) nm, Mr=538.64, Z=2, F(000)=542, Dc=1.822 g·cm-3, T=298(2) K, μ=1.435 mm-1 and λ=0.071 073 nm. The structure was refined to R=0.045 8 and wR=0.123 1 for 1 489 observed reflections with I>2σ(I). The complex was valued for its antimicrobial activity against bacterial strands using the agar diffusion method. It was found to be active against the four test bacterial organisms. CCDC: 600198. |
Keywords: cadmium complex tren 2-methylimidazole crystal structure antimicrobial activity |
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许同桃,许兴友,高健,倪帅帅,王大奇,杨绪杰,陆路德,徐国想.三(2-氨基乙基)胺-镉(Ⅱ)-2-甲基咪唑三元配合物的合成、结构与抗微生物活性(英文)[J].无机化学学报,2007,23(1):128-132. |
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