| 顺式-二(硫氰酸根)·二氨合铂(Ⅱ)的合成、表征及其水溶液析出物质机制的探讨 |
| Synthesis and Characterization of Cis-diaminedithiocyanatoplatinum(Ⅱ) and Study on Mechanism of a Precipitation from the Aqueous Solution |
|
| 摘要: |
| 关键词: 顺式-二(硫氰酸根/异硫氰酸根)·二氨合铂 铂配合物 硫氰酸根/异硫氰酸根 水溶液 |
| 基金项目: |
| Abstract: Cis-diaminedithiocyanatoplatinum(Ⅱ) (cis-[Pt(SCN)2(NH3)2]) was prepared and characterized through content analysis of Pt, MS, IR. The results show that the complex has cis configuration and the bond type of Pt and SCN- is Pt-S. When the aqueous solution of the complex was stored for one week, an orange-yellow precipitation appeared, different from the complex with light yellow color. Further comparative studies of these two complexes suggested that the precipitation is cis-[Pt(NCS)2(NH3)2], the linkage isomerism of cis-[Pt(SCN)2(NH3)2]. The mechanism of the isomerism reaction is also discussed. |
| Keywords: cis-diaminedithiocyanato/isothiocyanatoplatinum(Ⅱ) platinum complex thiocyanato/isothiocyanato aqueous solution |
| |
| 摘要点击次数: 1218 |
| 全文下载次数: 2 |
| 刘洋,余尧,高文桂,谌喜珠,谢笑天,刘伟平.顺式-二(硫氰酸根)·二氨合铂(Ⅱ)的合成、表征及其水溶液析出物质机制的探讨[J].无机化学学报,2006,22(11):2090-2096. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
