| 配合物[Sm(o-MOBA)3(phen)·H2O]2·4H2O的合成与晶体结构(英文) | |
| Synthesis and Crystal Structure of the Complex [Sm(o-MOBA)3(phen)·H2O]2·4H2O | |
| 摘要: | |
| 关键词: 邻-甲氧基苯甲酸 1，10-邻菲罗啉 晶体结构 钐配合物 | |
| 基金项目: | |
| Abstract: The title complex [Sm(o-MOBA)3(phen)·H2O]2·4H2O has been synthesized by the reaction of SmCl3·6H2O with o-methoxybenzoic acid and 1,10-phenanthroline in 1∶3∶1 molar ratio. The crystal structure was determined by X-ray single crystal diffraction. The crystal belongs to triclinic system, space group P1 with a=1.203(10) nm, b=1.293(10) nm, c=1.306(11) nm, α=64.50(10)°, β=81.93(10)°, γ=74.81(10)°. The molecular structure shows that the Sm3+ ion coordinates to nine atoms. The carboxylate groups are bonded to the samarium ion in three modes: monodentate, bidentate chelating, tridentate chelating-bridging. CCDC: 603740. | |
| Keywords: o-methoxybenzoic acid 1,10-phenanthroline crystal structure samarium complex | |
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| 任宁,张建军,宿素玲,张海燕,王瑞芬,王淑萍.配合物[Sm(o-MOBA)3(phen)·H2O]2·4H2O的合成与晶体结构(英文)[J].无机化学学报,2006,22(10):1905-1907. | |
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