| Shiff碱茚(1，2-b)喹喔啉-11-酮缩氨基硫脲合钴(Ⅱ)配合物的合成、表征与晶体结构 |
| Synthesis and Crystal Structure of the Indene[1,2-b]Quinoxalin-11-Alkone Thiosemicarbazone Cobalt(Ⅱ) Schiff Complex |
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| 摘要: |
| 关键词: Schiff碱 喹喔啉 钴(Ⅱ)配合物 单晶结构 |
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| Abstract: The title complex [CoL2](OH)Cl·1.1DMF (1) was synthesized (where L is Indene[1,2-b]Quinoxalin-11-Alkone Thiosemicarbazone) and characterized by elemental analysis, MS and X-ray single crystal structural analysis. The crystal structure 1 belongs to monoclinic system with space group C2/c, a=2.236 5(2) nm, b=1.990 4(2) nm, c=1.850 0(1) nm, β=116.576(2)°, V=7.365 2(9) nm3, Z=8. Each Co(Ⅱ) atom lies at the centre of a distorted coordination octahedron, formed by two L tridentate chelating ligands. The structure of the ligand L is nearly a plane. CCDC: 297352. |
| Keywords: Shiff base quinoxalin cobalt(Ⅱ) complex crystal structure |
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| 车喜全,王立斌.Shiff碱茚(1，2-b)喹喔啉-11-酮缩氨基硫脲合钴(Ⅱ)配合物的合成、表征与晶体结构[J].无机化学学报,2006,22(10):1857-1860. |
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