| 一个新颖三维配位聚合物Pb(1，4-napdc)(DMF)的合成、结构及热稳定性研究(英文) | |
| Synthesis, Crystal Structure and Thermal Stability of a Novel 3D Coordination Polymer Pb(1,4-napdc)(DMF) | |
| 摘要: | |
| 关键词: 铅(Ⅱ)配合物 气相扩散法 四方格子骨架结构 | |
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| Abstract: A novel 3D metal-organic coordination polymer Pb(1,4-napdc)(DMF) (1,4-napdc=naphthalene-1,4-dicarboxylate) was synthesized at room temperature using slow vapor diffusion method to grow single crystal that has been analyzed by X-ray diffraction. The crystal belongs to orthorhombic with space group P212121. The unit cell parameters are as fellows: a=0.701 3(2) nm, b=1.407 6(3) nm, c=1.521 5(4) nm, V=1.501 8(6) nm3 and Z=4. In the crystal structure of Pb(1,4-napdc)(DMF), the square grids constructed with paddle-wheel units of Pb(Ⅱ) and 1,4-napdc links stack over each other to generate infinite 3D network, which has square apertures (1.158×1.158 nm2) along the crystallographic a-axis. The thermal stability of compound was investigated by differential scanning calorimetry and thermogravimetric analysis. CCDC: 293617. | |
| Keywords: lead(Ⅱ) complex vapor diffusion synthesis square grid framework | |
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| 吴瑞凤,张同来,乔小晶,张建国,刘艳红.一个新颖三维配位聚合物Pb(1，4-napdc)(DMF)的合成、结构及热稳定性研究(英文)[J].无机化学学报,2006,22(7):1340-1344. | |
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