CoO填充多壁碳纳米管作为锂离子电池负极材料 |
CoO-filled Carbon Nanotubes as Insertion Anode Material for Lithium Batteries |
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摘要: |
关键词: 多壁碳纳米管 CoO 锂离子电池 负极材料 |
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Abstract: The electrochemical performance of CoO-filled multi-walled carbon nanotubes(MWCNTs) is described. MWCNTs were purified, opened and filled with cobalt salt in one-step by wet-chemistry route. Followed by calcinations in Ar atmosphere, the salt filled in the MWCNTs decomposed to CoO subsequently. Structural characterization of the composite material by X-ray diffraction and transmission electron microscopy showed that MWCNTs were filled by discrete nano-size CoO. Compared to the MWCNTs purified by HNO3, the CoO-filled MWCNTs exhibited higher capacity and better cyclability during galvanastatic charge-discharge cycling and cyclic voltammetry (CV) tests. |
Keywords: MWCNTs CoO lithium-ion batteries anode materials |
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叶茂,周震,卞锡奎,高学平,阎杰.CoO填充多壁碳纳米管作为锂离子电池负极材料[J].无机化学学报,2006,22(7):1307-1311. |
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