CoO填充多壁碳纳米管作为锂离子电池负极材料
CoO-filled Carbon Nanotubes as Insertion Anode Material for Lithium Batteries
作者单位
叶茂 南开大学新能源材料化学研究所天津 300071 
周震 南开大学新能源材料化学研究所天津 300071 
卞锡奎 南开大学新能源材料化学研究所天津 300071 
高学平 南开大学新能源材料化学研究所天津 300071 
阎杰 南开大学新能源材料化学研究所天津 300071 
摘要: 
关键词: 多壁碳纳米管  CoO  锂离子电池  负极材料
基金项目: 
Abstract: The electrochemical performance of CoO-filled multi-walled carbon nanotubes(MWCNTs) is described. MWCNTs were purified, opened and filled with cobalt salt in one-step by wet-chemistry route. Followed by calcinations in Ar atmosphere, the salt filled in the MWCNTs decomposed to CoO subsequently. Structural characterization of the composite material by X-ray diffraction and transmission electron microscopy showed that MWCNTs were filled by discrete nano-size CoO. Compared to the MWCNTs purified by HNO3, the CoO-filled MWCNTs exhibited higher capacity and better cyclability during galvanastatic charge-discharge cycling and cyclic voltammetry (CV) tests.
Keywords: MWCNTs  CoO  lithium-ion batteries  anode materials
 
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叶茂,周震,卞锡奎,高学平,阎杰.CoO填充多壁碳纳米管作为锂离子电池负极材料[J].无机化学学报,2006,22(7):1307-1311.
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