| 共价键连卟啉-富勒烯化合物的合成与表征 | |||||||||||||
| Synthesis and Characterization of Covalently Linked Porphyrin-fullerene Compounds | |||||||||||||
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| 关键词: 卟啉 富勒烯 金属卟啉 | |||||||||||||
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| Abstract: The covalently linked porphyrin-fullerene dyads were synthesized. The ligand 5-[4′-(4″-Phenoxybutoxy)phenyl]-N-(2-methyl)fulleropyrrolidine-10,15,20-tri-(p-methoxyphenyl)porphyrin (H2P-C60) was synthesized by 1,3 dipolar cycloaddition reaction with C60, sarcosine and H2P-CHO. The zinc porphyrin-fullerene was prepared by metalation of H2P-C60 and zinc acetate. The compounds were characterized by meams of IR, UV-Vis, ESI-MS, elemental analysis, and 1H NMR. | |||||||||||||
| Keywords: porphyrin fullerene metal porphyrin | |||||||||||||
| 摘要点击次数: 1286 | |||||||||||||
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| 凡素华,杨森根,吴振奕,陈昕,詹梦熊.共价键连卟啉-富勒烯化合物的合成与表征[J].无机化学学报,2006,22(7):1299-1302. | |||||||||||||
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