| SCN-桥联的一维链配位聚合物[Cd(dafo)(SCN)2]n的合成及晶体结构(英文) |
| Synthesis and Crystal Structure of Thiocyanato Bridged One Dimensional Polymeric Complex of Cadmium(Ⅱ) |
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| 摘要: |
| 关键词: Cd(Ⅱ) 晶体结构 dafo SCN-桥联 |
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| Abstract: A new one-dimensional compound [Cd(dafo)(SCN)2]n(dafo=4,5-diazafluoren-9-one) has been synthesized and characterized by single crystal X-ray diffraction. It crystallizes in the orthorhombic system; space group Pbca with a=1.708 6(5), b=1.303 6(4), c=2.592 6(8) nm, V=5.775(3) nm3, and Z=16. The crystal structure revealed that the structure of [Cd(dafo)(SCN)2]n features μ-1,3-thiocyante bridges and 1D chains. It consists of octahedrally coordinated Cd atoms. Both Cd(1) and Cd(2) are surrounded by two nitrogen atoms from dafo, two S atoms and two N atoms from two di-μ-1,3 thiocyanato bridges. CCDC: 251185. |
| Keywords: cadmium(Ⅱ) crystal structure 4,5-diazafluoren-9-one thiocyanato bridging |
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| 赵琦华,王丽,王昆淼,方瑞斌.SCN-桥联的一维链配位聚合物[Cd(dafo)(SCN)2]n的合成及晶体结构(英文)[J].无机化学学报,2006,22(7):1285-1288. |
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