室温电化学沉积Ba1-xCaxMoO4多晶固溶体薄膜 |
Electrochemical Deposition of Ba1-xCaxMoO4 Polycrystalline Solid-solution Thin Film at Room Temperature |
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摘要: |
关键词: Ba1-xCaxMoO4薄膜 固溶体 电化学沉积 |
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Abstract: At room temperature, Ba1-xCaxMoO4 polycrystalline solid solution thin films were prepared directly in contained Ca2+ and Ba2+ alkaline solution by electrochemical anode oxidation method. The crystal phase structure, surface morphology, ratio of compositions and room temperature fluorescence properties of the as-grown films were measured by using XRD, SEM, EDAX and Fluorescence Analysis techniques, respectively. The results reveal that the ratio of composition of Ba1-xCaxMoO4 films can be modulated by controlling the ratio of Ca2+ and Ba2+ in starting solutions; moreover it has important influence of ratio of composition of the films on the grain growth, the crystal lattice constant, the surface morphology as well as the fluorescence properties of the as-grown films. |
Keywords: Ba1-xCaxMoO4 thin films solid solution electrochemical deposition |
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毕剑,余萍,陈连平,金晓玲,赖欣,肖定全.室温电化学沉积Ba1-xCaxMoO4多晶固溶体薄膜[J].无机化学学报,2006,22(5):909-912. |
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