可见光催化剂S/TiO2的制备与表征
Preparation and Characterization of Visible-light Responsive Photocatalyst S/TiO2
作者单位
王永强 哈尔滨工业大学市政环境工程学院哈尔滨 150090 
于秀娟 哈尔滨工业大学市政环境工程学院哈尔滨 150090
黑龙江大学环境科学与工程系哈尔滨 150080 
杨红芬 哈尔滨工业大学市政环境工程学院哈尔滨 150090 
明 琪 哈尔滨工业大学市政环境工程学院哈尔滨 150090 
孙德智 哈尔滨工业大学市政环境工程学院哈尔滨 150090 
摘要: 
关键词: S掺杂  光催化  可见光  苯甲酸
基金项目: 
Abstract: The sulfur-doped titanium dioxide (S/TiO2) was prepared by calcinations. The photocatalytic decomposition of benzoic acid solution was carried out under simulated sun light; the photocatalytic activity is 2.7 times of TiO2. The results of XRD show that the sulfur can restrain the crystallization transformation of TiO2 from anatase to rutile, although the calcinations temperature has attained 500 ℃, the crystallization still is anatase entirely. The responsive wavelength range of S/TiO2 was shifted; it has obvious absorption in the region from 320 to 550 nm. The S (S6+) substituted for some of the lattice titanium atoms in S/TiO2. At the same time the XRF also prove the formation of S6+ and the atomic content is 2.13%.
Keywords: sulfur-doped  photocatalytic  visible-light  benzoic acid
 
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王永强,于秀娟,杨红芬,明 琪,孙德智.可见光催化剂S/TiO2的制备与表征[J].无机化学学报,2006,22(4):771-774.
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