| Abstract: The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group
P1 with a=1.142 8(3) nm, b=1.638 8(4) nm, c=1.645 6(4) nm, α=74.428(5)°, β=84.205(5)°, γ=74.917(5)°, V=2.864 9(12)
nm3, Dc=1.347 g·cm-3. Z=2, F(000)=1 216, the reliability factor
R1=0.068 9, wR2=0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 274184. |
| 杨颖群,李昶红,邝代治,郭栋才,陈志敏,陈满生,匡云飞.配合物[Ni(phen)3][(C6H5)2C(OH)COO]2·6H2O的合成、晶体结构及电化学性质[J].无机化学学报,2006,22(2):303-306. |
