| 四-α-(2，2，4-三甲基-3-戊氧基)酞菁金属配合物(M=Co，Ni，Cu，Zn)的合成与光谱性质(英) |
| Synthesis and Spectroscopic Property of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) Phthalocyaninato] Metal Complexes (M=Co, Ni, Cu, Zn) |
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| 摘要: |
| 关键词: 酞菁金属配合物 光谱性质 构造异构体 |
| 基金项目: |
| Abstract: A series of [tetra-α-(2,2,4-tirmethyl-3-pentoxy) phthalocyaninato] metal complexes(M=Co, Ni, Cu, Zn)were prepared by cyclotetramerization of 3-(2,2,4-tirmethyl-3-pentoxy)phthalonitrile with corresponding anhydrous metal salts， using 1.8-diazabicyclo[5.4.0] undec-7-ene (DBU) as the catalyst. HPLC analysis shows that one isomer predominates in the product of nickel complex, while at least two main constitutional isomers exist in the product of other metal complexes. The complexes (in the form of mixture of constitutional isomers) were characterized by elemental analyses, MS, IR and UV-Vis spectroscopy. |
| Keywords: phthalocyaninato metal complex spectroscopic property constitutional isomer |
| 投稿时间：2005-05-23 修订日期：2005-07-26 |
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| 江舟,陈耐生,王俊东,黄金陵.四-α-(2，2，4-三甲基-3-戊氧基)酞菁金属配合物(M=Co，Ni，Cu，Zn)的合成与光谱性质(英)[J].无机化学学报,2005,21(12):1891-1896. |
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