LiV3O8的合成及其电化学性能研究
Synthesis and Electrochemical Properties of LiV3O8
作者单位
李海霞 南开大学新能源材料化学研究所天津 300071 
焦丽芳 南开大学新能源材料化学研究所天津 300071 
袁华堂 南开大学新能源材料化学研究所天津 300071 
赵明 南开大学新能源材料化学研究所天津 300071 
王永梅 南开大学新能源材料化学研究所天津 300071 
摘要: 
关键词: 溶胶-凝胶法  LiV3O8  电化学性能
基金项目: 
Abstract: The layered trivanadate, LiV3O8, was prepared by sol-gel method with LiOH, V2O5 and H2O2 as initial reagents. The materials at different heat treatment conditions were characterized by XRD and TG-DTA. Their electrochemical behaviors were studied by galvanostatic charge-discharge and cyclic voltammetry. The results show that LiV3O8 prepared by sintering at 300 ℃ for 16 h has higher capacity, and its initial discharge capacity is 333.1 mAh·g-1, and maintains a discharge capacity of 302.8 mAh·g-1 after 10 cycles at 0.2 C and the voltage range of 1.8~4.0 V.
Keywords: sol-gel method  LiV3O8  electrochemical properties
投稿时间:2005-04-11 修订日期:2005-07-25
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李海霞,焦丽芳,袁华堂,赵明,王永梅.LiV3O8的合成及其电化学性能研究[J].无机化学学报,2005,21(12):1865-1868.
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