[{Zn(3-SBA)(2,2′-bipy)(H2O)2}·H2O]n的合成和晶体结构研究 |
Synthesis and Crystal Structure of [{Zn(3-SBA)(2,2′-bipy)(H2O)2}·H2O]n |
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摘要: |
关键词: 锌配合物 间苯甲酸磺酸钠(3-Na2SBA) 晶体结构 荧光性质 |
基金项目: |
Abstract: A novel coordination ploymer [{Zn(3-SBA)(2,2′-bipy)(H2O)2}·H2O]n was synthesized by the hydrothermal reaction of 3-Na2SBA, ZnSO4·7H2O and 2,2′-bipy. The structure was characterized by elemental analysis, IR and single crystal X-ray diffraction. The title coordination ploymer crystallized in monoclinic with space group P21, a=0.803 42(18) nm, b=1.501 8(3) nm, c=0.821 13(19) nm, β=109.350(4)°. The coordination polymer has an infinite chain structure and its luminescent property has also been studied. CCDC: 282746. |
Keywords: Zn complex 3-Na2SBA crystal structure photoluminescence |
投稿时间:2005-08-29 修订日期:2005-10-06 |
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李文戈,王作为,蔡亚,许正江,李一志,郑和根.[{Zn(3-SBA)(2,2′-bipy)(H2O)2}·H2O]n的合成和晶体结构研究[J].无机化学学报,2005,21(12):1857-1860. |
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