1,4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构 |
Synthesis and Crystal Structure of a Novel Self-assembled (1,4-discyclohexyl cucurbituril) Sodium(Ⅰ) Complex |
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摘要: |
关键词: 1,4-二环己基取代六元瓜环 晶体结构 自组装实体 |
基金项目: |
Abstract: A novel complex of a new 1,4-dicyclohexyl cucurbituril(DCYQ[6]) with sodium(Ⅰ) ion was synthesized, and the crystal structure was determined by X-ray diffraction technique. In this self-assembled entity both the cavity interaction of DCYQ[6] included a nitrate anion and the portal interaction of the dipole carbonyls of DCYQ[6] with sodium cations lead to form self assembled molecular capsules. The crystal structure of the entity shows a packing of the self assembled molecular capsules connected by hydrogen bonds of water molecules. CCDC: 271400. |
Keywords: 1,4-dicyclohexyl cucurbituril crystal structure self-assembled entity |
投稿时间:2004-10-25 修订日期:2005-08-04 |
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郑利梅,祝黔江,朱建男,张云黔,陶朱,薛赛凤,魏赞斌,龙腊生.1,4二环己基取代六元瓜环与Na(Ⅰ)自组装实体的合成与晶体结构[J].无机化学学报,2005,21(10):1583-1588. |
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